瞬态吸收显微镜
瞬态吸收(TA)实验能够对光激发样品的随时间变化的吸收情况进行定量表征。该技术需要两束光脉冲:一束是飞秒窄带宽泵浦脉冲,用于激发样品;另一束是延迟的宽带宽探测脉冲,用于测量样品透射率的变化。所得到的差分吸收信号会作为探测波长以及泵浦脉冲与探测脉冲之间时间延迟的函数被测量。
瞬态吸收光谱比稳态吸收光谱或荧光衰减光谱等要复杂得多。它不仅能提供系统激发态的信息,还能给出基态和激发态中所有中间演化瞬态以及非辐射态的相关信息。
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